{"id":6783,"date":"2025-09-02T15:03:14","date_gmt":"2025-09-02T06:03:14","guid":{"rendered":"https:\/\/aquaphotomics.com\/ja\/?page_id=6783"},"modified":"2025-09-18T13:29:02","modified_gmt":"2025-09-18T04:29:02","slug":"fundamental-studies","status":"publish","type":"page","link":"https:\/\/aquaphotomics.com\/ja\/fundamental-studies\/","title":{"rendered":"\u57fa\u790e\u7814\u7a76"},"content":{"rendered":"\n

\u672c\u306e\u795e\u6238\u5927\u5b66\u751f\u4f53\u8a08\u6e2c\u5de5\u5b66\u7814\u7a76\u5ba4\u306eRoumiana Tsenkova\u6559\u6388\u306f\u53ef\u8996-\u8fd1\u8d64\u5916\u5206\u5149\u6cd5\u3092\u7528\u3044\u3066\u3001\u751f\u4f53\u30b7\u30b9\u30c6\u30e0\u306e\u8a3a\u65ad\u3001\u6c34\u304a\u3088\u3073\u6c34\u6eb6\u6db2\u7cfb\u306e\u7814\u7a76\u3092\u9577\u5e74\u3057\u305f\u306e\u3061\u3001\u4ed6\u306e\u300c\u30aa\u30df\u30af\u30b9\u300d\u5206\u91ce\u3092\u88dc\u5b8c\u3059\u308b\u65b0\u3057\u3044\u300c\u30aa\u30df\u30af\u30b9\u300d\u5206\u91ce\u3068\u3057\u3066\u3001\u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u306e\u5275\u7acb\u3092\u63d0\u5531\u3057\u307e\u3057\u305f\u3002\uff08Tsenkova 2006d, b, a, c, 2009\uff09 \u3057\u304b\u3057\u306a\u304c\u3089\u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u306f\u305d\u308c\u3060\u3051\u3067\u306a\u304f\u3001\u6c34\u306e\u7814\u7a76\u3001\u6c34\u3068\u5149\u306e\u76f8\u4e92\u4f5c\u7528\u306b\u95a2\u3059\u308b\u65e2\u5b58\u306e\u8c4a\u5bcc\u306a\u77e5\u8b58\u306e\u4f53\u7cfb\u5316\u3001\u305d\u3057\u3066\u65b0\u3057\u3044\u73fe\u8c61\u306e\u767a\u898b\u3092\u5c02\u9580\u306b\u884c\u3046\u3082\u306e\u306a\u306e\u3067\u3059\u3002 \u6c34\u3092\u7814\u7a76\u3059\u308b\u305f\u3081\u306b\u3053\u308c\u307e\u3067\u306b\u591a\u304f\u306e\u624b\u6cd5\u304c\u7528\u3044\u3089\u308c\u305f\u306b\u3082\u304b\u304b\u308f\u3089\u305a\u3001\u305d\u306e\u69cb\u9020\u306f\u3082\u3061\u308d\u3093\u3001\u6c34\u5358\u72ec\u306e\u6a5f\u80fd\u6027\u3082\u3044\u307e\u3060\u89e3\u660e\u3055\u308c\u3066\u3044\u307e\u305b\u3093\u3002 \u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u306e\u7814\u7a76\u304c\u793a\u3057\u305f\u306e\u306f\u3001\u8fd1\u8d64\u5916\u5206\u5149\u6cd5\u3001\u304a\u3088\u3073\u4e00\u822c\u306b\u96fb\u78c1\u30b9\u30da\u30af\u30c8\u30eb\u5168\u4f53\u306b\u308f\u305f\u308b\u6c34\u3068\u5149\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u3001\u6c34\u306e\u79d1\u5b66\u5206\u91ce\u3068\u6c34\u5206\u5b50\u30b7\u30b9\u30c6\u30e0\u306e\u3088\u308a\u826f\u3044\u7406\u89e3\u306b\u5927\u304d\u304f\u8ca2\u732e\u3067\u304d\u308b\u3068\u3044\u3046\u3053\u3068\u3067\u3059\u3002\uff08Tsenkova2009\uff09<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u306f\u3001\u3044\u308f\u3086\u308b\u300c\u30a6\u30a9\u30fc\u30bf\u30fc\u30df\u30e9\u30fc\u30a2\u30d7\u30ed\u30fc\u30c1\u300d\u306b\u57fa\u3065\u3044\u3066\u304a\u308a\u3001\u6c34\u6eb6\u6db2\u7cfb\u306e\u3059\u3079\u3066\u306e\u5468\u56f2\u306e\u6210\u5206\u3068\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u6c34\u306e\u69cb\u9020\u306b\u5f71\u97ff\u3092\u4e0e\u3048\u307e\u3059\u3002 \u6442\u52d5\u306f\u6c34\u306e\u5206\u5b50\u5f62\u614b\u306b\u5909\u5316\u3092\u3082\u305f\u3089\u3057\u3001\u305d\u308c\u304c\u6c34\u30b9\u30da\u30af\u30c8\u30eb\u306b\u53cd\u6620\u3055\u308c\u307e\u3059\u3002 \u6c34\u7d20\u7d50\u5408\u306e\u611f\u5ea6\u304c\u975e\u5e38\u306b\u9ad8\u3044\u305f\u3081\u3001\u6eb6\u8cea\u7d44\u6210\u306e\u308f\u305a\u304b\u306a\u5909\u5316\u3067\u3055\u3048\u3001\u6c34\u69cb\u9020\u4f53\u306b\u591a\u304f\u306e\u5909\u5316\u3092\u3082\u305f\u3089\u3057\u3001\u5438\u53ce\u30b9\u30da\u30af\u30c8\u30eb\u30d1\u30bf\u30fc\u30f3\u306b\u93e1\u306e\u3088\u3046\u306b\u53cd\u6620\u3055\u308c\u307e\u3059\u3002\u3053\u306e\u3088\u3046\u306b\u6c34\u306e\u5438\u53ce\u30d0\u30f3\u30c9\u306e\u5909\u5316\u3092\u5206\u6790\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u9593\u63a5\u7684\u306b\u73fe\u5728\u306e\u6eb6\u8cea\u306b\u95a2\u3059\u308b\u60c5\u5831\u3092\u5f97\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p>\n\n\n\n

\u8fc5\u901f\u3067\u975e\u7834\u58ca\u7684\u3067\u3042\u308b\u305f\u3081\u3001\u8fd1\u8d64\u5916\u5206\u5149\u6cd5\u306f\u9014\u65b9\u3082\u306a\u304f\u5fdc\u7528\u7bc4\u56f2\u306e\u5e83\u3044\u5f37\u529b\u306a\u624b\u6cd5\u3067\u3042\u308a\u3001\u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u306f\u305d\u306e\u8996\u91ce\u3092\u5e83\u3052\u307e\u3057\u305f\u3002\u30a6\u30a9\u30fc\u30bf\u30fc\u30df\u30e9\u30fc\u30a2\u30d7\u30ed\u30fc\u30c1\u306b\u3088\u3063\u3066\u4ee5\u524d\u306f\u4e0d\u53ef\u80fd\u3068\u8003\u3048\u3089\u308c\u3066\u3044\u305fppm\u30ec\u30d9\u30eb\u3067\u306e\u6fc3\u5ea6\u6e2c\u5b9a\u304c\u53ef\u80fd\u3068\u306a\u308a\u307e\u3059\u3002\uff08Tsenkova 2008b,Sakudo et al.2006, Gowen, Amigo, and Tsenkova 2013, B\u00e1z\u00e1r et al. 2015, B\u00e1z\u00e1r et al. 2014\uff09 \u3055\u3089\u306b\u7279\u5b9a\u6761\u4ef6\u4e0b\u306e\u5b9f\u9a13\u3067\u306fppb\u30ec\u30d9\u30eb\u306e\u6e2c\u5b9a\u5024\u3092\u63d0\u4f9b\u3057\u307e\u3059\u3002\uff08Tsenkova 2008a, b, Tsenkova et al. 2007, Sakudo et al. 2005, Sakudo et al. 2006\uff09 \u305d\u306e\u6982\u5ff5\u3092\u5b9f\u8a3c\u3059\u308b\u7814\u7a76\u306e1\u3064\u3067\u306f\u3001\u3055\u307e\u3056\u307e\u306a\u5869\u306e\u6fc3\u5ea6\u3092 0.002\u301c0.1mol\/L\u306e\u7bc4\u56f2\u3067\u6e2c\u5b9a\u3059\u308b\u3053\u3068\u3092\u76ee\u7684\u3068\u3057\u3066\u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u30b9\u30da\u30af\u30c8\u30eb\u5206\u6790\u3092\u9069\u7528\u3057\u307e\u3057\u305f\u3002\uff08Gowen et al.2015\uff09 NIR\u30b9\u30da\u30af\u30c8\u30eb\u3092\u793a\u3055\u306a\u3044\u6eb6\u8cea\u7cfb\u306e\u30e2\u30c7\u30eb\u3068\u3057\u3066\u5869\u3092\u4f7f\u7528\u3057\u3066\u3044\u308b\u305f\u3081\u3001\u5f97\u3089\u308c\u308b\u7d50\u679c\u306f\u3001\u5b8c\u5168\u306b\u6c34\u306e\u5438\u53ce\u30d0\u30f3\u30c9\u304c\u5909\u5316\u3059\u308b\u3053\u3068\u3088\u308b\u3082\u306e\u3067\u3059\u3002\u3053\u308c\u306f\u3001\u3053\u306e\u3088\u3046\u306a\u4f4e\u6fc3\u5ea6\u306e\u5869\u306e\u5f71\u97ff\u3092\u8abf\u3079\u305f\u6700\u521d\u306e\u7814\u7a76\u3067\u3057\u305f\u3002\u30a6\u30a9\u30fc\u30bf\u30fc\u30df\u30e9\u30fc\u30a2\u30d7\u30ed\u30fc\u30c1\u306b\u3088\u308a\u691c\u51fa\u9650\u754c1000ppm\u30ec\u30d9\u30eb\u3067\u306e\u6fc3\u5ea6\u4e88\u6e2c\u304c\u53ef\u80fd\u3068\u306a\u308b\u3053\u3068\u304c3\u3064\u306e\u7814\u7a76\u5ba4\u3067\u7570\u306a\u308b\u5206\u5149\u6e2c\u5b9a\u30b7\u30b9\u30c6\u30e0\u3092\u7528\u3044\u3066\u5b9f\u8a3c\u3055\u308c\u307e\u3057\u305f\u3002\u3055\u3089\u306b\u30a6\u30a9\u30fc\u30bf\u30fc\u30df\u30e9\u30fc\u30a2\u30d7\u30ed\u30fc\u30c1\u3092\u9069\u7528\u3057\u3066\u3001\u5358\u7cd6\u304a\u3088\u3073\u4e8c\u7cd6\u985e\u306e100\u301c0.02 mM\u6fc3\u5ea6\u306e\u5b9a\u91cf\u6e2c\u5b9a\u304c\u5b9f\u65bd\u3055\u308c\u307e\u3057\u305f\u3002\uff08B\u00e1z\u00e1r et al.2015\uff09 \u3053\u308c\u306f\u3001\u8fd1\u8d64\u5916\u5206\u5149\u6cd5\u306b\u3088\u3063\u3066\u30df\u30ea\u30e2\u30e9\u6fc3\u5ea6\u306e\u5358\u7cd6\u304a\u3088\u3073\u4e8c\u7cd6\u985e\u3092\u691c\u51fa\u9650\u754c0.1\u301c1mM\u3067\u5b9a\u6027\u30fb\u5b9a\u91cf\u5206\u6790\u53ef\u80fd\u3067\u3042\u308b\u3053\u3068\u3092\u78ba\u8a8d\u3057\u305f\u6700\u521d\u306e\u7814\u7a76\u3068\u306a\u308a\u307e\u3057\u305f\u3002\u3053\u306e\u30a2\u30d7\u30ed\u30fc\u30c1\u3092\u9069\u7528\u3059\u308b\u3053\u3068\u3067\u3001\u5206\u6790\u5bfe\u8c61\u7269\u306e\u6fc3\u5ea6\u306e\u307b\u304b\u306b\u3001pH\u3084\u9178\u6027\u5ea6\u306a\u3069\u6c34\u5206\u5b50\u30b7\u30b9\u30c6\u30e0\u306e\u3044\u304f\u3064\u304b\u306e\u7269\u7406\u30d1\u30e9\u30e1\u30fc\u30bf\u30fc\u306e\u6e2c\u5b9a\u306b\u3082\u6210\u529f\u3057\u307e\u3057\u305f\u3002\uff08Omar, Atan, and Matjafri 2012\uff09<\/p>\n\n\n\n

\u5927\u898f\u6a21\u306a\u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u306e\u7814\u7a76\u7d50\u679c\u306e\u4f53\u7cfb\u5316\u306b\u3088\u308a\u3001\u30a4\u30aa\u30f3\u306e\u5468\u8fba\u90e8\u306b\u6349\u3048\u3089\u308c\u305f\u6c34\u5206\u5b50\u306e\u5438\u53ce\u30d0\u30f3\u30c9\uff081398nm\uff09\u306a\u3069\u306e\u3044\u304f\u3064\u304b\u306e\u65b0\u3057\u3044\u5438\u53ce\u30d0\u30f3\u30c9\uff08Koji\u0107 et al.2014\uff09\u3084\u3001\u3055\u3089\u306b\u306f\u3001\u6c34\u69cb\u9020\u4f53\u5ea7\u6a19\u9818\u57df\uff08WAter MAtrics CoordinateS \u2013 WAMACS\uff09\u3068\u3088\u3070\u308c\u308b\u305d\u308c\u305e\u308c\u306e\u6a5f\u80fd\u306b\u95a2\u9023\u3057\u305f\u7279\u5b9a\u306e\u6c34\u306e\u5438\u53ce\u30d0\u30f3\u30c9\u304c\u6700\u3082\u9ad8\u3044\u78ba\u7387\u3067\u898b\u3089\u308c\u308b\u30b9\u30da\u30af\u30c8\u30eb\u9818\u57df\u304c\u767a\u898b\u3055\u308c\u307e\u3057\u305f\u3002\uff08Tsenkova2009\uff09 \u300c\u5ea7\u6a19\u300d\u3068\u3044\u3046\u8a00\u8449\u304c\u4f7f\u7528\u3055\u308c\u308b\u306e\u306f\u3001\u3053\u308c\u3089\u304c\u96fb\u78c1\u30b9\u30da\u30af\u30c8\u30eb\u5185\u306e\u4f4d\u7f6e\u3067\u3042\u308a\u3001\u305d\u3053\u3067\u306f\u6e2c\u5b9a\u3055\u308c\u305f\u6c34\u306e\u5438\u5149\u5ea6\u304c\u305d\u306e\u6c34\u306b\u7279\u6709\u306a\u69cb\u9020\u306e\u3055\u307e\u3056\u307e\u306a\u6c34\u5206\u5b50\u7cfb\u300c\u30d3\u30eb\u30c7\u30a3\u30f3\u30b0\u30d6\u30ed\u30c3\u30af\u300d\u306b\u95a2\u3059\u308b\u60c5\u5831\u3092\u4f1d\u3048\u3001\u6c34\u6eb6\u6db2\u7cfb\u306e\u30c0\u30a4\u30ca\u30df\u30af\u30b9\u3092\u89b3\u5bdf\u3067\u304d\u308b\u304b\u3089\u3067\u3059\u3002 WAMACS\u306f\u60c5\u5831\u306e\u30cf\u30d6\u3068\u8003\u3048\u308b\u3053\u3068\u304c\u3067\u304d\u3001\u7279\u5b9a\u306e\u6c34\u5206\u5b50\u69cb\u9020\u306b\u5272\u308a\u5f53\u3066\u3089\u308c\u3066\u3044\u307e\u3059\u3002\uff08Tsenkova 2009, Tsenkova, Kovacs, and Kubota 2015\uff09 \u6c34\u306e\u7b2c1\u500d\u97f3\u306b\u3064\u3044\u3066\u306f\u300112\u500b\u306eWAMAC\uff08Ci, i = 1\u301c12\u3068\u8868\u8a18\uff09\u304c\u5b9f\u9a13\u7684\u306b\u767a\u898b\u3055\u308c\uff08\u305d\u308c\u305e\u308c\u5e456\u301c20 nm\uff09\u3001\u3053\u308c\u3089\u306e\u4e2d\u306b\u306f\u8d64\u5916\u9818\u57df\u3067\u3059\u3067\u306b\u5831\u544a\u3055\u308c\u3066\u3044\u308b\u6c34\u306e\u5438\u53ce\u30d0\u30f3\u30c9\u304b\u3089\u306e\u500d\u97f3\u8a08\u7b97\u306b\u3088\u3063\u3066\u78ba\u8a8d\u3055\u308c\u3066\u3044\u308b\u3082\u306e\u304c\u3042\u308a\u307e\u3059\u3002\uff08Tsenkova2009\uff09 \u3053\u306e\u3088\u3046\u306b\u3001\u30a2\u30af\u30a2\u30d5\u30a9\u30c8\u30df\u30af\u30b9\u306f\u3001\u6c34\u3068\u5149\u306e\u76f8\u4e92\u4f5c\u7528\u306b\u95a2\u3059\u308b\u57fa\u790e\u7684\u306a\u77e5\u898b\u306b\u5bc4\u4e0e\u3057\u3001\u5fdc\u7528\u3078\u5411\u3051\u305f\u65b0\u305f\u306a\u60c5\u5831\u3068\u9769\u65b0\u306e\u53ef\u80fd\u6027\u3092\u3082\u305f\u3089\u3057\u307e\u3057\u305f\u3002<\/p>\n\n\n\n

B\u00e1z\u00e1r, G., Z. Kovacs, M. Tanaka, A. Furukawa, A. Nagai, M. Osawa, Y. Itakura, H. Sugiyama, and R. Tsenkova. 2015. \u201cWater revealed as molecular mirror when measuring low concentrations of sugar with near infrared light.\u201d  Analytica chimica acta<\/em> 896:52-62.<\/p>\n\n\n\n

B\u00e1z\u00e1r, G., Z. Kov\u00e1cs, M. Tanaka, and R. Tsenkova. 2014. \u201cAquaphotomics and its extended water mirror concept explain why NIRS can measure low concentration aqueous solutions.\u201d Aquaphotomics,\u201cUnderstanding Water in Biological World\u201d, The 5th Kobe University Brussels European Centre Symposium \u201cInnovation, Environment, and Globalisation\u201d, Brussels, Belgium.<\/p>\n\n\n\n

Gowen, A., J. Amigo, and R. Tsenkova. 2013. \u201cCharacterisation of hydrogen bond perturbations in aqueous systems using aquaphotomics and multivariate curve resolution-alternating least squares.\u201d  Analytica chimica acta<\/em> 759:8-20.<\/p>\n\n\n\n

Gowen, A., F. Marini, Y. Tsuchisaka, S. De Luca, M. Bevilacqua, C. O\u2019Donnell, G. Downey, and R. Tsenkova. 2015. \u201cOn the feasibility of near infrared spectroscopy to detect contaminants in water using single salt solutions as model systems.\u201d  Talanta<\/em> 131:609-618.<\/p>\n\n\n\n

Koji\u0107, D., R. Tsenkova, K. Tomobe, K. Yasuoka, and M. Yasui. 2014. \u201cWater confined in the local field of ions.\u201d  ChemPhysChem<\/em> 15 (18):4077-4086. doi: 10.1002\/cphc.201402381.<\/p>\n\n\n\n

Omar, A.F., H. Atan, and M.Z. Matjafri. 2012. \u201cNIR spectroscopic properties of aqueous acids solutions.\u201d  Molecules<\/em> 17 (6):7440-7450.<\/p>\n\n\n\n

Sakudo, A., R. Tsenkova, T. Onozuka, K. Morita, S. Li, J. Warachit, Y. Iwabu, G. Li, T. Onodera, and K. Ikuta. 2005. \u201cA novel diagnostic method for human immunodeficiency virus Type\u20101 in plasma by near\u2010infrared spectroscopy.\u201d  Microbiology and immunology<\/em> 49 (7):695-701.<\/p>\n\n\n\n

Sakudo, A., R. Tsenkova, K. Tei, T. Onozuka, K. Ikuta, E. Yoshimura, and T. Onodera. 2006. \u201cComparison of the vibration mode of metals in HNO3 by a partial least-squares regression analysis of near-infrared spectra.\u201d  Bioscience, biotechnology, and biochemistry<\/em> 70 (7):1578-1583.<\/p>\n\n\n\n

Tsenkova, R. 2006a. \u201cAquaphotomics. Aquaphotomics and Chambersburg.\u201d  NIR news<\/em> 17 (6):12-0.<\/p>\n\n\n\n

Tsenkova, R. 2006b. \u201cAquaphotomics: exploring water-light interactions for a better understanding of the biological world. Part 2: Japanese food, language and why NIR for diagnosis?\u201d  NIR news<\/em> 17 (5):8-14.<\/p>\n\n\n\n

Tsenkova, R. 2006c. \u201cAquaPhotomics: water absorbance pattern as a biological marker.\u201d  NIR news<\/em> 17 (7):13-0. doi: 10.1255\/nirn.926.<\/p>\n\n\n\n

Tsenkova, R. 2006d. Tomas Hirschfeld Award Lecture. Orlando, Florida, USA.<\/p>\n\n\n\n

Tsenkova, R. 2008a. \u201cAquaphotomics: acquiring spectra of various biological fluids of the same organism reveals the importance of water matrix absorbance coordinates and the aquaphotome for understanding biological phenomena.\u201d  NIR news<\/em> 19 (1):13-15.<\/p>\n\n\n\n

Tsenkova, R. 2008b. \u201cAquaphotomics: the extended water mirror effect explains why small concentrations of protein in solution can be measured with near infrared light.\u201d  NIR news<\/em> 19 (4):13-14.<\/p>\n\n\n\n

Tsenkova, R. 2009. \u201cAquaphotomics: dynamic spectroscopy of aqueous and biological systems describes peculiarities of water.\u201d  Journal of Near Infrared Spectroscopy<\/em> 17 (6):303-313. doi: 10.1255\/jnirs.869.<\/p>\n\n\n\n

Tsenkova, R., E. Iso, M. Parker, C. Fockenberg, and M. Okubo. 2007. \u201cAquaphotomics: a NIRS investigation into the perturbation of water spectrum in an aqueous suspension of mesoscopic scale polystyrene spheres.\u201d 13th international conference on near infrared spectroscopy, Umea-Vasa, Sweden & Finland.<\/p>\n\n\n\n

Tsenkova, R., Z. Kovacs, and Y. Kubota. 2015. \u201cAquaphotomics: near infrared spectroscopy and water states in biological systems.\u201d In Membrane Hydration<\/em>, 189-211. Springer.<\/p>\n","protected":false},"excerpt":{"rendered":"

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